Speed Ratio Relation (v_mp : v_avg : v_rms = √2 : √(8/π) : √3 ≈ 1.414 : 1.596)

jee-mainjee-advanced

v_mp : v_avg : v_rms = √2 : √(8/π) : √3 ≈ 1.414 : 1.596 : 1.732

What each symbol means

SymbolWhat it stands for
MMolar mass (kg/mol)
RUniversal gas constant = 8.314 J mol⁻¹ K⁻¹
TAbsolute temperature (K)
v_mpMost probable speed — speed at which Maxwell distribution peaks (m/s)
v_avgMean (average) speed — arithmetic mean of all molecular speeds (m/s)
v_rmsRoot mean square speed — √(⟨v²⟩), always the largest (m/s)

When to use this

Valid for ideal gas obeying Maxwell-Boltzmann speed distribution. Ratio is UNIVERSAL — independent of gas type, temperature, or pressure. Individual speeds depend on T and M, but ratio cancels out. Always: v_mp < v_avg < v_rms.