Fajan's rules: covalent character (Smaller/higher-charge cation polarizes larger anion → more covalent character)

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Smaller/higher-charge cation polarizes larger anion → more covalent character

What each symbol means

SymbolWhat it stands for
z/rPolarizing power of cation (qualitative)
anion sizeLarger anion more polarizable

When to use this

Qualitative trends for melting point, solubility, colour in some cases.